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We have calculated experimentally and analyzed theoretically the Ti 2p X-ray photoemission spectra (XPS) as well as the resonant enhancement of valence photoemissionat the Ti 2p threshold for Ti2O3.
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It can be demonstrated the O 1s resonant XES delivers information on the Cu-associated excitations such as the Cu dd e...
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The pre-edge structure of Cu1s excitations of high Tc cuprates displays the bottom-lying unoccupied electronic states in these resources, and thus it truly is specifically relevant into the intriguing very low-Strength excitations and their nonlocal figures.
The spectral broadening on the excitation spectrum is determined because of the M5 core gap lifetime, staying free of charge from the L3 Main hole lifet...
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The Ni2p X-ray photoemission spectrum (XPS) for NiCl2 is reanalyzed on the basis of a NiCl64− cluster product. By considering the electron configuration dependence of your hybridization strengths amongst Ni3d and Cl3p orbitals, we display which the design can consistently reproduce the experimental 2p-XPS plus the energy gap of your program.
Owing to the large covalency in LaCuO3, the photoabsorption at a selected Cu web-site triggers the electronic excitation at neighboring Cu sites. The excitation Strength on the distant Cu web pages contributes on the ener...
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The double-peak function from the Cu 2p photoabsorption line shape of LaCuO3 is talked about on The premise of large-cluster-design calculations.